全文获取类型
收费全文 | 1290篇 |
免费 | 52篇 |
国内免费 | 125篇 |
专业分类
化学 | 723篇 |
晶体学 | 6篇 |
力学 | 553篇 |
综合类 | 21篇 |
数学 | 31篇 |
物理学 | 133篇 |
出版年
2023年 | 8篇 |
2022年 | 9篇 |
2021年 | 26篇 |
2020年 | 30篇 |
2019年 | 33篇 |
2018年 | 24篇 |
2017年 | 52篇 |
2016年 | 38篇 |
2015年 | 52篇 |
2014年 | 32篇 |
2013年 | 87篇 |
2012年 | 59篇 |
2011年 | 49篇 |
2010年 | 58篇 |
2009年 | 92篇 |
2008年 | 85篇 |
2007年 | 84篇 |
2006年 | 84篇 |
2005年 | 97篇 |
2004年 | 82篇 |
2003年 | 52篇 |
2002年 | 44篇 |
2001年 | 31篇 |
2000年 | 29篇 |
1999年 | 26篇 |
1998年 | 22篇 |
1997年 | 23篇 |
1996年 | 25篇 |
1995年 | 24篇 |
1994年 | 25篇 |
1993年 | 19篇 |
1992年 | 13篇 |
1991年 | 14篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 9篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有1467条查询结果,搜索用时 15 毫秒
81.
Different novel phthalazino[2,3‐b]phthalazine‐5,7,12,14‐tetraones were synthesized in a simple and environmentally benign method from the reaction of phthalic anhydrides with semicarbazide or thiosemicarbazide using montmorillonite K‐10 clay as solid heterogeneous acidic catalyst and microwaves under solvent‐free conditions in good yields and short reaction times. Products were characterized by the elemental analysis, IR, NMR, and mass spectrometry. 相似文献
82.
83.
Cu含量对Cu/Al-Ce-PILC上丙烯选择性催化还原NO反应的影响 总被引:3,自引:0,他引:3
采用聚合羟基复合阳离子合成交联粘土Al-Ce-PILC,经SO2-4改性后,以浸渍法制备了用于C3H6选择性还原NO反应的铜基交联粘土催化剂Cu/Al-Ce-PILC. 用XRD,XPS和TPR等技术对催化剂进行了表征,并考察了Cu含量对催化剂性能的影响. 结果表明,Cu负载未改变Al-Ce-PILC的结构; w(Cu)=2%时,Cu物种以Cu+和Cu2+两种形式存在,催化剂具有最高的催化活性和较宽的操作温度范围,在反应气组成为0.22%NO-0.12%C3H6-2.0%O2-97.66%He,空速为 24000 h-1和温度为350 ℃的条件下,NO转化率可达56.4%,700 ℃下仍可达22.3%; w(Cu)=5%时,催化剂中有明显的CuO物相存在,该物相促进C3H6的深度氧化,从而降低了NO选择性还原反应的性能. 相似文献
84.
Hans E. Miltner Christophe Block Guy Van Assche Kurt Van Durme Bogdan Bogdanov 《European Polymer Journal》2010,46(5):984-996
A comprehensive overview of available methods for assessing nanofiller dispersion is presented for a wide range of layered silicate-based poly(ε-caprolactone) (PCL) nanocomposites. Focusing on their respective strengths and weaknesses, rheological, mechanical and thermal characterization approaches are evaluated in direct relation to morphological information. Pronounced changes in the rheological and mechanical properties of the materials are only observed for nanocomposites displaying the highest nanofiller dispersion levels, as confirmed by an innovative and highly reliable thermal analysis approach based on quasi-isothermal crystallization. As such, the data obtained from the different methods also allow a detailed investigation of the crucial factors affecting nanofiller dispersion, evidencing the importance of specific matrix/filler interactions and the need for proper melt processing conditions when targeting significant property enhancements. Finally, the wide potential of the developed methodologies for the characterization of polymeric nanocomposites in general is illustrated by an extension to carbon nanotube-based PCL composites, unambiguously demonstrating their complementarity and broad applicability. 相似文献
85.
Robert J. Bellair Mihai Manitiu Esin Gulari Rangaramanujam M. Kannan 《Journal of Polymer Science.Polymer Physics》2010,48(8):823-831
Superior property enhancements in polymer–clay nanocomposites can be achieved if one can significantly enhance the nanoclay dispersion and polymer–clay interactions. Recent studies have shown that nanoclays can be dispersed in polymers using supercritical carbon dioxide (scCO2). However, there is need for a better understanding of how changing the clay modifier affects the clay dispersability by scCO2 and the resultant nanocomposite rheology. To address this, the polystyrene (PS)/clay nanocomposites with “weak” interaction (Cloisite 93A clay) and “strong” interaction (Cloisite 15A clay) have been prepared using the supercritical CO2 method in the presence of a co‐solvent. Transmission electron microscopy images and small‐angle X‐ray diffraction illustrate that composites using 15A and 93A clays show similar magnitude of reduction in the average tactoid size, and dispersion upon processing with scCO2. When PS and the clays are coprocessed in scCO2, the “dispersion” of clays appears to be independent of modifier or polymer–clay interaction. However, the low‐frequency storage modulus in the scCO2‐processed 15A nanocomposites is two orders of magnitude higher than that of 93A nanocomposites. It is postulated that below percolation (solution blended composites), the strength of polymer–clay interaction is not a significant contributor to rheological enhancement. In the scCO2‐processed nanocomposites the enhanced dispersion passes the percolation threshold and the interactions dictate the reinforcement potential of the clay–polymer–clay network. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 823–831, 2010 相似文献
86.
Ravi Aggarwal Durairaj Baskaran 《Journal of polymer science. Part A, Polymer chemistry》2011,49(23):5049-5056
Hydrated sodium montmorillonite (Na‐clay) has been used as a catalyst support for the heterogeneous atom transfer radical polymerization of benzyl methacrylate in the presence of various concentrations of water, reducing agent, and CuBr2 in anisole at ambient temperature. The polymerization was promoted via reduction of CuII to CuI through the addition of sodium ascorbate (NaAsc) as a reducing agent in aqueous solution. The polymerizaton proceeded in a controlled manner and produced poly(benzyl methacylate) with moderately narrow molecular weight distribution (MWD) when performed under optimum conditions of hydration (10 wt % ≤ H2O/Na‐clay ≤ 21 wt %) and reducing agent (0.15 ≤ [NaAsc]/[I] ≤ 0.23). The polymerization was uncontrolled if hydration and NaAsc exceed above their optimum range of concentrations. Apparent rate of the polymerization (kapp) increased in the presence of decane–anisole (1/3, v/v) mixture solvent. Selective adsorption of decane at the interfaces of the hydrated clay was attributed for the rate enhancement due to increased polymer and hydrophobic interface interaction. The polymerization progressed in a controlled manner as confirmed by the first‐order time‐conversion plot, linear increase in molecular weights, and moderately narrow MWDs over conversion. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
87.
Kazem Jeddi Nader Taheri Qazvini Seyed Hassan Jafari Hossein Ali Khonakdar Javad Seyfi Uta Reuter 《Journal of Polymer Science.Polymer Physics》2011,49(4):318-326
Polymer–silicate nanocomposites based on poly (ethylene oxide), PEO, poly(methyl methacrylate), PMMA, and sodium montmorillonite clay were fabricated and characterized to investigate the effect of nanolayered silicates on segmental dynamics of PEO/PMMA blends. X‐ray results indicate the formation of an exfoliated morphology in the nanocomposites. At low silicate contents, an enhancement in segmental dynamics of blend nanocomposites and also PEO, minor component in blend, is observed at temperature region below blend glass transition. This result can be attributed to the improvement of the confinement effect of rigid PMMA matrix on the PEO chains by introducing a low amount of layered silicates. On the other hand, at high silicate contents, an enhancement in segmental dynamics of blend nanocomposites and PEO is observed at temperature region above blend glass transition. This behavior could be interpreted based on the reduction of monomeric friction between two polymer components, which can facilitate segmental motions of blend components in nanocomposite systems. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
88.
Intercalated nanocomposites of modified montmorillonite clays in a glassy epoxy were prepared by crosslinking with commercially available aliphatic diamine curing agents. These materials are shown to have improved Young's modulus but corresponding reductions in ultimate strength and strain to failure. The results were consistent with most particulate‐filled systems. The macroscopic compressive behavior was unchanged, although the failure mechanisms in compression varied from the unmodified samples. The fracture toughness of these materials was investigated and improvements in toughness values of 100% over unmodified resin were demonstrated. The fracture‐surface topology was examined using scanning electron and tapping‐mode atomic force microscopies and shown to be related to the clay morphology of the system. © 2001 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 1137–1146, 2001 相似文献
89.
György Szöllsi Ágnes Mastalir Mihály Bartók 《Reaction Kinetics and Catalysis Letters》2001,74(2):241-249
Clay-supported platinum catalysts were prepared by ion exchange. The platinum precursor has been reduced either in the presence or in the absence of cinchonidinium cations introduced in the interlamellar space of the cationic clay. The samples were characterized by XRD and TEM. Reduction by NaBH4 in the absence of cinchonidinium cations and the subsequent introduction of this latter ensured the formation of monodispersed, small platinum crystallites immobilized mostly between the clay sheets. On the other hand, reduction in the presence of the organic cations resulted in migration of the platinum particles on the external surface of the clay. 相似文献
90.
Kübra Yumakgil Argun Talat Gökçeören Candan Erbil 《Journal of Polymer Science.Polymer Physics》2010,48(12):1256-1264
N‐isopropyl acrylamide (NIPAAm) hydrogels are known as thermosensitive crosslinked polymer networks. In this work, the network parameters of their composites, i.e., NIPAAm/sodium montmorillonite (NIPAAm/Na+MMT) hydrogels synthesized by free radical solution polymerization in the presence of two different types of accelerator (tetramethyl ethylenediamine (TEMED) and ethylenediamine tetraacetic acid (EDTA)) and initiator (potassium persulphate (K2S2O8) and cerium ammonium nitrate ((NH4)2Ce(NO3)6), Ce(IV)) using five different clay content (in the range of 1.0–5.0 wt % of total monomer concentration) at 25 °C were presented and discussed. FTIR spectra, XRD patterns, SEM photographs, and network parameters of the samples indicated that the presence of COOH groups on EDTA molecules was resulted in the formation of exfoliated structures and the activity of EDTA/KPS redox pair was higher than those of TEMED/KPS and EDTA/Ce (IV) pairs. The compression moduli (G) of the hydrogels initiated with EDTA/Ce(IV) redox pair showed smooth and continual changings with increase in Na+MMT content (for swelling equilibrium at 25 °C) on the contrary of EDTA/KPS and TEMED/KPS pairs. It might be related to low initiator efficiency of cerium ammonium nitrate than KPS molecules, having higher effective crosslinking density with increasing clay content. On the other hand, the G moduli of NIPAAm/Na+MMT hydrogels (above their phase transition temperature) initiated with TEMED/KPS redox pair were higher than the others because of the more hydrophobic nature of TEMED molecules. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1256–1264, 2010 相似文献